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Beilstein J. Org. Chem. 2015, 11, 1412–1417, doi:10.3762/bjoc.11.152
Graphical Abstract
Figure 1: Structures of photopyrones 1–8, pseudopyronines 9–11, myxopyronin A (12) and corallopyronin A (13)....
Scheme 1: Proposed biosynthesis of photopyrone D (4) by PpyS from P. luminescens. The second deprotonation st...
Figure 2: Dimeric structure of modeled PpyS (A). Chain A (blue), chain B (red). 14 (surface, cyan) is covalen...
Figure 3: Phylogenetic tree (PHYML) composed of PpyS, its homologues and other known ketosynthases. Table S4 (...